60Co-γ Radiolysis of Aqueous Ferro- and Ferricyanide Solutions
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Acetonylperoxyl Radicals, CH3C0CH20 2: A Study on the y-Radiolysis and Pulse Radiolysis of Acetone in Oxygenated Aqueous Solutions
Hydroxyl radicals from the radiolysis of N20 / 0 2 (4:l)-saturated aqueous solutions of acetone (10 3 mol dm -3) react with the solute by H-abstraction thereby forming acetonyl radicals. As shown by pulse radiolysis, the acetonyl radicals rapidly add oxygen (k = 3 x 109 dm3m ol_1s_1) thereby forming acetonylperoxyl radicals which decay by second-order kinetics (2 k = 8 x 10* dm3mol 's -1). Unde...
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ژورنال
عنوان ژورنال: RADIOISOTOPES
سال: 1967
ISSN: 1884-4111,0033-8303
DOI: 10.3769/radioisotopes.16.9_434